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无乳化剂的交联型ABA三元嵌段共聚物纳米粒子

来源:林中祥胶粘剂技术信息网2011年10月06日

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Emulsifier-free Synthesis of Crosslinkable ABA Triblock Copolymer Nanoparticles via AGET ATRP

Technical Paper - A crosslinkable ABA triblock copolymer was synthesized from allylic methacrylate (AMA) monomer using a poly(ethylene oxide)-based macromolecule as both an initiator and emulsifier. The "two-step" controlled/living radical polymerization can be conducted via activator generated by electron transfer (AGET) atom transfer radical polymerization (ATRP). Cheap and commercially available N,N-dimethyldodecylamine (DMDA) was found to be a good ligand for the AGET ATRP reaction. The linear ABA triblock copolymer that contains pendent allylic groups can undergo crosslinking under UV irradiation conditions, which indicates that the environmentally friendly method has potential applications in UV curing coatings and UV curing inks, etc.. (c) 2011 The Polymer Society of Korea and Springer Netherlands.

Source : EIX 11-39 E20113714331631 NDN- 267-0982-7846-3 AUTHORS- Cheng, Chuanjie EMAIL- chengcj530@gmail.com AUTHORS- Fu, Quanlei AUTHORS- Liu, Zhongbin AUTHORS- Shen, Liang EMAIL- shenliang00@tsinghua.org.cn AUTHORS- Qiao, Yongluo AUTHORS- Fu, Changqing AUTHOR ADDRESS- Fenglin Street, Nanchang, Jiangxi 330013 ABBREVIATED JOURNAL TITLE- Macromol. Res. VOLUME 19 NUMBER 10 PUBLICATION DATE- October 2011 1048-1055 PAGES 51 REFERENCES DOCUMENT TYPE- Journal Article ISSN- 1598-5032 PUBLICATION DATE- 2011 AUTHOR AFFILIATION- Cheng, C.; Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Fenglin Street, Nanchang, Jiangxi 330013, chengcj530@gmail.com, CHINA PUBLISHER- Polymer Society of Korea, Room 601, Hatchon B/D, 831 Yeoksam-dong, Kangnam-ku, Seoul, 135-792 PUBLICATION COUNTRY- KOREA, REPUBLIC OF JOURNAL NAME- Macromolecular Research ELECTRONIC JOURNALS DOCUMENT NUMBER- 2092-7673 DOCUMENT URL- 10.1007/s13233-011-1008-4 LANGUAGE- English
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